What Drives Radical Halogenation versus Hydroxylation in Mononuclear Nonheme Iron Complexes? A Combined Experimental and Computational Study
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DOI: 10.1021/jacs.2c01375
Abstract: Nonheme iron halogenases are unique enzymes in nature that selectively activate an aliphatic C–H bond of a substrate to convert it into C–X (X = Cl/Br, but not F/I). It is proposed that they generate… read more here.
Keywords: secondary carbon; transfer; iron; halogenation ... See more keywords