Molecular Engineering of the Kinetic Barrier in Seeded Supramolecular Polymerization
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10482
Abstract: Seeded supramolecular polymerization (SSP) is a method that enables the controlled synthesis of supramolecular structures. SSP often relies on structures that are capable of self-assembly by interconverting between intramolecular and intermolecular modes of hydrogen bonding,… read more here.
Keywords: seeded supramolecular; supramolecular polymerization; hydrogen; kinetic barrier ... See more keywords
Distinct seed topologies enable comparison of elongation and secondary nucleation pathways in seeded supramolecular polymerization.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01587d
Abstract: The influence of seed topologies on seeded supramolecular polymerization was examined using helicoidal and toroidal supramolecular polymer seeds. The addition of these seeds to a supersaturated solution of monomers led to distinct nucleation-growth kinetics, which… read more here.
Keywords: supramolecular polymerization; seeded supramolecular; nucleation; seed topologies ... See more keywords