Seeking Redox Activity in a Tetrazinyl Pincer Ligand: Installing Zerovalent Cr and Mo.
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DOI: 10.1021/acs.inorgchem.8b01761
Abstract: Reaction of the readily reduced pincer ligand bis-tetrazinylpyridine, btzp, with the zerovalent metal source M(CO)3(MeCN)3 yields M(btzp)2 for M = Cr, Mo. These diamagnetic molecules show intrapincer bond lengths consistent with major charge transfer from… read more here.
Keywords: pincer; metal; zerovalent; seeking redox ... See more keywords