Cp*Co(III)-Catalyzed γ-Selective C-H Allylation/Hydroamination Cascade for the Synthesis of Dihydroisoquinolines.
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DOI: 10.1021/acs.orglett.9b03977
Abstract: A Cp*Co(III)-catalyzed γ-selective C-H allylation/hydroamination cascade toward the synthesis of 3,4-dihydroisoquinolines (DHIQs) has been successfully developed, starting from NH ketimines and allyl carbonates. Notably, highly efficient and γ-selective C-H allylations were accomplished using γ-substituted allyl… read more here.
Keywords: selective allylation; allylation hydroamination; hydroamination cascade; catalyzed selective ... See more keywords
Platinum-catalyzed selective N-allylation of 2,3-disubstituted indoles with allylic acetates in water
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DOI: 10.1039/c8nj05051a
Abstract: Herein, we have demonstrated that the platinum-catalyzed selective N-allylation of 2,3-disubstituted indoles proceeds in water. read more here.
Keywords: allylation disubstituted; selective allylation; disubstituted indoles; platinum catalyzed ... See more keywords
Rh-Catalyzed diastereo- and linear-selective α-allylation of chiral cycloenamines
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DOI: 10.1039/d0qo01087a
Abstract: In this paper, a Rh-catalyzed diastereoselective α-allylation of cycloenamines is demonstrated. read more here.
Keywords: diastereo linear; selective allylation; allylation; catalyzed diastereo ... See more keywords