Palladium-Catalyzed Three-Component Selective Aminoallylation of Diazo Compounds.
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DOI: 10.1021/acs.orglett.2c01399
Abstract: We describe a Xantphos-containing dinuclear palladium complex-enabled geminal aminoallylation of diazocarbonyl compounds, which selectively provides a range of quaternary α-amino esters. Direct N-H insertion, allylic alkylation of amino nucleophiles, and diene formation were not observed… read more here.
Keywords: component selective; aminoallylation; palladium catalyzed; catalyzed three ... See more keywords