Metal Nanoparticles Confined within Inorganic-Organic Framework Enables Superior Substrate-Selective Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c10814
Abstract: The search for catalysts with a perfect substrate-selectivity towards the hydrogenation of nitroarenes is a goal of high importance, which still remains a significant challenge at present. Here, we designed a new type of catalysts… read more here.
Keywords: selective catalysis; superior substrate; metal nanoparticles; substrate selective ... See more keywords
Surface-Modified Nanozymes for Enhanced and Selective Catalysis
Sign Up to like & getrecommendations! Published in 2025 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.5c07647
Abstract: Surface-modified catalytic nanoparticles (nanozymes) are introduced as hybrid nanoparticles overcoming basic limitations associated with bare nanozymes that include moderate catalytic turnovers, lack of substrate selectivity and chiroselectivity, and poor or nonselective permeabilities into biomembrane. This… read more here.
Keywords: selective catalysis; enhanced selective; surface modified; nanozymes enhanced ... See more keywords
Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc00676a
Abstract: How the crystal structures of ordered transition-metal phosphide catalysts affect the hydrogen-evolution reaction (HER) is investigated by measuring the anisotropic catalytic activities of selected crystallographic facets on large (mm-sized) single crystals of iron-phosphide (FeP) and… read more here.
Keywords: phosphide catalysts; facet selective; surface; single crystals ... See more keywords
Light-switched selective catalysis with NADH mimic functionalized metal-organic capsules.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04530c
Abstract: By incorporating an active site model of nicotinamide adenine dinucleotide (NADH) as an electron regulator, a redox-active metal-organic capsule as an efficient photocatalyst was obtained for the light switchable synthesis of a series of aromatic… read more here.
Keywords: light switched; selective catalysis; switched selective; metal organic ... See more keywords
Size-selective catalysis enhancement in a new nanocaged MOF through constructing synergistic Lewis acidic-basic sites effect
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Materials Chemistry A"
DOI: 10.1039/d5ta03725e
Abstract: Metal–organic frameworks (MOFs) with small pore window sizes and narrow internal space always suffer from low diffusion rate of reactants/products, and limited accessibility to their internal catalytic active sites, resulting... read more here.
Keywords: enhancement new; size selective; selective catalysis; nanocaged mof ... See more keywords
In situ engineered matched pockets for efficient substrate-selective catalysis in complex mixtures: synergistic binding-catalysis in magnetic imprinted nanoreactors
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Materials Chemistry A"
DOI: 10.1039/d5ta05327g
Abstract: An enzyme-mimic matched pockets for efficient substrate-selective catalysis in complex mixtures. read more here.
Keywords: selective catalysis; matched pockets; efficient substrate; pockets efficient ... See more keywords
Electric field–induced selective catalysis of single-molecule reaction
Sign Up to like & getrecommendations! Published in 2019 at "Science Advances"
DOI: 10.1126/sciadv.aaw3072
Abstract: A cascade chemical reaction is selectively activated through oriented external electric field at the single-molecule scale. Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by orienting the alignment of the… read more here.
Keywords: single molecule; selective catalysis; reaction; induced selective ... See more keywords