Metal Nanoparticles Confined within Inorganic-Organic Framework Enables Superior Substrate-Selective Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c10814
Abstract: The search for catalysts with a perfect substrate-selectivity towards the hydrogenation of nitroarenes is a goal of high importance, which still remains a significant challenge at present. Here, we designed a new type of catalysts… read more here.
Keywords: selective catalysis; superior substrate; metal nanoparticles; substrate selective ... See more keywords
Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystalsâ€
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc00676a
Abstract: How the crystal structures of ordered transition-metal phosphide catalysts affect the hydrogen-evolution reaction (HER) is investigated by measuring the anisotropic catalytic activities of selected crystallographic facets on large (mm-sized) single crystals of iron-phosphide (FeP) and… read more here.
Keywords: phosphide catalysts; facet selective; surface; single crystals ... See more keywords
Light-switched selective catalysis with NADH mimic functionalized metal-organic capsules.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04530c
Abstract: By incorporating an active site model of nicotinamide adenine dinucleotide (NADH) as an electron regulator, a redox-active metal-organic capsule as an efficient photocatalyst was obtained for the light switchable synthesis of a series of aromatic… read more here.
Keywords: light switched; selective catalysis; switched selective; metal organic ... See more keywords
Electric field–induced selective catalysis of single-molecule reaction
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DOI: 10.1126/sciadv.aaw3072
Abstract: A cascade chemical reaction is selectively activated through oriented external electric field at the single-molecule scale. Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by orienting the alignment of the… read more here.
Keywords: single molecule; selective catalysis; reaction; induced selective ... See more keywords