Selective C−C Coupling by Spatially Confined Dimeric Metal Centers
Sign Up to like & getrecommendations! Published in 2020 at "iScience"
DOI: 10.1016/j.isci.2020.101051
Abstract: Summary Direct conversion of carbon dioxide (CO2) to high-energy fuels and high-value chemicals is a fascinating sustainable strategy. For most of the current electrocatalysts for CO2 reduction, however, multi-carbon products are inhibited by large overpotentials… read more here.
Keywords: spatially confined; carbon; metal; selective coupling ... See more keywords
Wavelength-Selective Coupling and Decoupling of Polymer Chains via Reversible [2 + 2] Photocycloaddition of Styrylpyrene for Construction of Cytocompatible Photodynamic Hydrogels
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00099
Abstract: Reversible photocycloaddition reactions have previously been employed in chemical cross-linking for the preparation of biomaterial scaffolds. However, the processes require activation by high-energy UV light, rendering them unsuitable for modification in biological environments. Here we… read more here.
Keywords: photocycloaddition styrylpyrene; reversible photocycloaddition; wavelength selective; photocycloaddition ... See more keywords
Wavefront Shaping of Plasmonic Beams by Selective Coupling
Sign Up to like & getrecommendations! Published in 2017 at "ACS Photonics"
DOI: 10.1021/acsphotonics.7b00346
Abstract: Custom plasmonic beams are advantageous for numerous scientific and technological aspects. While plasmonic wavefront shaping had traditionally been a truly planar process, taking place on a single surface, here we explore a new method for… read more here.
Keywords: beams selective; selective coupling; shaping plasmonic; wavefront shaping ... See more keywords
Ligand-Enabled Selective Coupling of MIDA Boronates to Dehydroalanine-Containing Peptides and Proteins.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c16525
Abstract: α,β-dehydroalanine (ΔAla) is a uniquely reactive nonproteinogenic amino acid often employed for the late-stage functionalization of peptides, natural products (NPs), and proteins. The modification of ΔAla is a powerful method for the semisynthetic engineering of… read more here.
Keywords: chemistry; selective coupling; ligand enabled; peptides proteins ... See more keywords
Enantiotopic-group-selective coupling for unified access to carbazole atropisomers as versatile chiral chromophores
Sign Up to like & getrecommendations! Published in 2025 at "Nature Communications"
DOI: 10.1038/s41467-025-65243-8
Abstract: Chiral organic chromophores are foundational for advanced optical and electronic devices. Despite the widespread use of N-aryl carbazoles in visible-luminescent materials, chiroptical applications of their atropisomers have remained underdeveloped due to the synthetic challenge of… read more here.
Keywords: selective coupling; enantiotopic group; group selective; chiral chromophores ... See more keywords
Key to C2 production: selective C-C coupling for electrochemical CO2 reduction on copper alloy surfaces.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc03796j
Abstract: The C-C coupling kinetic variations are observed on Cu alloys with Pt, Pd, or Au surface sites. The OC-COH coupling is kinetically more favorable than OC-CHO coupling, which originates from increased reactivity of adsorbed *CO… read more here.
Keywords: production selective; production; coupling electrochemical; selective coupling ... See more keywords
Cu-catalyzed selective coupling of alkynes with danB-Bpai.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc05330g
Abstract: A novel diboronic reagent, danB-Bpai, has been designed, and the copper-catalyzed selective transformation reaction between alkynes and this reagent has been investigated. By regulating ligands and additives, the chemoselective reaction of danB-Bpai can be achieved.… read more here.
Keywords: reaction; coupling alkynes; catalyzed selective; selective coupling ... See more keywords
Theory of Polarization-Selective Coupling and Its Application to Design of Planar Orthomode Transducers
Sign Up to like & getrecommendations! Published in 2018 at "IEEE Transactions on Antennas and Propagation"
DOI: 10.1109/tap.2017.2778015
Abstract: With the rapid and continuous development of new generations of wireless technologies and networks, exploring the underutilized millimeter-wave (mm-wave) band becomes inescapable. Polarization diversity has been an essential factor in the performance and capacity enhancement… read more here.
Keywords: orthomode; polarization; selective coupling; polarization selective ... See more keywords