Ultra-Sensitive and Selective Electrochemical Bio-Fluid Biopsy for Oral Cancer Screening.
Sign Up to like & getrecommendations! Published in 2021 at "Small methods"
DOI: 10.1002/smtd.202001205
Abstract: The early diagnosis of recurrence and metastasis is critically important for decreasing the morbidity and mortality associated with oral cancers. Although liquid biopsy methods hold great promise that provide a successive "time-slice" profile of primary… read more here.
Keywords: selective electrochemical; cancer screening; cancer; liquid biopsy ... See more keywords
Single site porphyrine-like structures advantages over metals for selective electrochemical CO 2 reduction
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Today"
DOI: 10.1016/j.cattod.2017.02.028
Abstract: Abstract Currently, no catalysts are completely selective for the electrochemical CO2 Reduction Reaction (CO2RR). Based on trends in density functional theory calculations of reaction intermediates we find that the single metal site in a porphyrine-like… read more here.
Keywords: porphyrine like; reduction; site porphyrine; site ... See more keywords
Selective Electrochemical Oxygenation of Alkylarenes to Carbonyls.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02651
Abstract: An efficient electrochemical method for benzylic C(sp3)-H bond oxidation has been developed. A variety of methylarenes, methylheteroarenes, and benzylic (hetero)methylenes could be converted into the desired aryl aldehydes and aryl ketones in moderate to excellent… read more here.
Keywords: electrochemical oxygenation; oxygenation alkylarenes; alkylarenes carbonyls; selective electrochemical ... See more keywords
Selective Electrochemical Synthesis of 9-Aryl-10-sulfonyl Substituted Phenanthrene from Alkynes and Sulfonyl Hydrazides.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03948
Abstract: An efficient electrochemical synthesis of sulfonated phenanthrenes via the reaction of internal alkynes with sulfonyl hydrazides has been established. The protocol does not require a metal catalyst or external oxidants, providing a green and mild… read more here.
Keywords: electrochemical synthesis; alkynes sulfonyl; selective electrochemical; sulfonyl hydrazides ... See more keywords
Site-Selective Electrochemical Oxidation of Glycosides
Sign Up to like & getrecommendations! Published in 2023 at "ACS Catalysis"
DOI: 10.1021/acscatal.2c06318
Abstract: Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with high selectivity and good yields. The method is a versatile alternative to Pd-catalyzed or photochemical oxidation and is complementary to the 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-mediated C6-selective oxidation. Contrary… read more here.
Keywords: electrochemical oxidation; oxidation; site selective; oxidation glycosides ... See more keywords
High Selective Electrochemical Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol on RuO2–SnO2–TiO2/Ti Electrode
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03500
Abstract: Electrocatalytic hydrogenation is a promising method to synthesize high value-added chemicals under mild conditions. However, in the case of converting cinnamaldehyde (CAL) into cinnamyl alcohol (C... read more here.
Keywords: hydrogenation; high selective; cinnamyl alcohol; selective electrochemical ... See more keywords
Selective Electrochemical Decarboxylation of n-Octanoic Acid to Hydrocarbons on Pt Nanocrystals
Sign Up to like & getrecommendations! Published in 2021 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c08611
Abstract: Electrocatalytic synthesis of valuable biofuels and chemicals from biomass-derived acids is a promising approach, but selectively producing deoxygenated hydrocarbons is still a great challenge. In ... read more here.
Keywords: decarboxylation octanoic; selective electrochemical; acid hydrocarbons; octanoic acid ... See more keywords
Selective electrochemical determination of casein based on magnetic molecularly imprinted nanoparticles
Sign Up to like & getrecommendations! Published in 2019 at "Ferroelectrics"
DOI: 10.1080/00150193.2019.1653084
Abstract: Abstract The selective electrochemical determination of casein from bovine milk (consisting of α-s1 Casein, α-s2 Casein, β-Casein, and κ-Casein) was developed based on magnetic molecularly imprinted nanoparticles (MMIPs) modified on the carbon paste electrode. Superparamagnetic… read more here.
Keywords: magnetic molecularly; determination casein; based magnetic; electrochemical determination ... See more keywords
Cu2O-Ag Tandem Catalysts for Selective Electrochemical Reduction of CO2 to C2 Products
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26082175
Abstract: The electrochemical carbon dioxide reduction reaction (CO2RR) to C2 chemicals has received great attention. Here, we report the cuprous oxide (Cu2O) nanocubes cooperated with silver (Ag) nanoparticles via the replacement reaction for a synergetic CO2RR.… read more here.
Keywords: reduction; tandem catalysts; catalysts selective; electrochemical reduction ... See more keywords