Selective Heterogeneous Transfer Hydrogenation from Tertiary Amines to Alkynes
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c05186
Abstract: Hydrogen transfer reactions from tertiary amines to phenyl- and alkyl-substituted alkynes catalyzed by Pt and Pd supported on carbon are investigated. Evidence of a sequential two-cycle mechanism s... read more here.
Keywords: heterogeneous transfer; hydrogenation tertiary; transfer hydrogenation; tertiary amines ... See more keywords
Highly Selective Heterogeneous Ethylene Dimerization with a Scalable and Chemically Robust MOF Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05703
Abstract: Metal–organic frameworks (MOFs) hold great promise as structurally tunable catalysts capable of high selectivity in the solid state, yet their comparatively high cost and often limited stability remain significant concerns for their commercialization as heterogeneous… read more here.
Keywords: highly selective; heterogeneous ethylene; ethylene dimerization; dimerization ... See more keywords