Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(21)63853-6
Abstract: Abstract Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective. In this respect, catalytic deoxygenative amide reduction has proven to be promising but challenging, as this approach… read more here.
Keywords: zirconium hydride; bond cleavage; hydride catalyzed; selective hydroboration ... See more keywords
Markovnikov-Selective Hydroboration of Aryl Alkenes Catalyzed by Quaternary Ammonium Salts
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DOI: 10.1021/jacs.5c13555
Abstract: The development of catalytic Markovnikov-selective hydroboration of alkenes has seen significant progress; however, achieving this transformation under metal-free conditions has remained a longstanding challenge. Here, we present an organocatalytic method for the Markovnikov-selective hydroboration of… read more here.
Keywords: markovnikov selective; hydroboration aryl; quaternary ammonium; selective hydroboration ... See more keywords
Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes.
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DOI: 10.1021/jacs.7b11416
Abstract: A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination of N-heteroarenes to the iron… read more here.
Keywords: selective hydroboration; catalyzed selective; hydroboration heteroarenes; heteroarenes iron ... See more keywords
Highly efficient and selective hydroboration of terminal and internal alkynes catalysed by a cobalt(ii) coordination polymer
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DOI: 10.1039/c9qo00834a
Abstract: Selective hydroboration of terminal and internal alkynes is catalysed using a CoII-coordination polymer precatalyst with TOFs of up to 47 520 h−1. read more here.
Keywords: terminal internal; internal alkynes; selective hydroboration; coordination polymer ... See more keywords