Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(21)63853-6
Abstract: Abstract Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective. In this respect, catalytic deoxygenative amide reduction has proven to be promising but challenging, as this approach… read more here.
Keywords: zirconium hydride; bond cleavage; hydride catalyzed; selective hydroboration ... See more keywords
Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11416
Abstract: A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination of N-heteroarenes to the iron… read more here.
Keywords: selective hydroboration; catalyzed selective; hydroboration heteroarenes; heteroarenes iron ... See more keywords
Highly efficient and selective hydroboration of terminal and internal alkynes catalysed by a cobalt(ii) coordination polymer
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00834a
Abstract: Selective hydroboration of terminal and internal alkynes is catalysed using a CoII-coordination polymer precatalyst with TOFs of up to 47 520 h−1. read more here.
Keywords: terminal internal; internal alkynes; selective hydroboration; coordination polymer ... See more keywords