A Magnetically Separable Pd Single‐Atom Catalyst for Efficient Selective Hydrogenation of Phenylacetylene
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202110455
Abstract: Selective hydrogenation of alkynes to alkenes plays a crucial role in the synthesis of fine chemicals. However, how to achieve high selectivity and effective separation of the catalyst and substrate while obtaining high activity is… read more here.
Keywords: hydrogenation phenylacetylene; catalyst; hydrogenation; single atom ... See more keywords
General Strategy toward Hydrophilic Single Atom Catalysts for Efficient Selective Hydrogenation
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202202144
Abstract: Well dispersible and stable single atom catalysts (SACs) with hydrophilic features are highly desirable for selective hydrogenation reactions in hydrophilic solvents towards important chemicals and pharmaceutical intermediates. A general strategy is reported for the fabrication… read more here.
Keywords: general strategy; hydrogenation; single atom; selective hydrogenation ... See more keywords
Adjustment of the single atom/nanoparticle ratio in Pd/CNT catalysts for phenylacetylene selective hydrogenation
Sign Up to like & getrecommendations! Published in 2023 at "ChemCatChem"
DOI: 10.1002/cctc.202300036
Abstract: Pd/C catalysts are widely used for hydrogenation reactions in the chemical industry. One of the reasons for their high activity is the ability of Pd nanoparticles (PdNP) to dissociate H2 and promote H‐spillover. Nevertheless, for… read more here.
Keywords: hydrogenation; pdsa; single atom; selective hydrogenation ... See more keywords
Selective hydrogenation of HMF to 1-hydroxy-2,5-hexanedione by biochar supported Ru catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200437
Abstract: The development of sustainable and efficient catalysts namely Ru supported activated biochars was carried out for the selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 1-hydroxy-2,5-hexanedione (HHD). In particular, the activated biochars (A Lw and A HSw… read more here.
Keywords: hmf hydroxy; hydroxy hexanedione; hmf; selective hydrogenation ... See more keywords
Single-Atom Catalysts for Hydrogen Activation.
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DOI: 10.1002/smll.202300956
Abstract: Selective hydrogenation is one of the most important reactions in fine chemical industry, and the activation of H2 is the key step for hydrogenation. Catalysts play a critical role in selective hydrogenation, and some single-atom… read more here.
Keywords: hydrogenation; single atom; selective hydrogenation; atom catalysts ... See more keywords
Shape/Crystal Facet of Ceria Induced Well-Dispersed and Stable Au Nanoparticles for the Selective Hydrogenation of Phenylacetylene
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Letters"
DOI: 10.1007/s10562-018-02648-9
Abstract: A series of CeO2 with the morphology of nanocube (NC), nanopolyhedron (NP) and nanorod (NR) were synthesized by hydrothermal method as substrates to support monometallic Au catalysts. Insight into support morphology-dependent the property of active… read more here.
Keywords: selective hydrogenation; dispersed stable; hydrogenation phenylacetylene; well dispersed ... See more keywords
Vapour Phase Selective Hydrogenation of Furfural to Furfuryl Alcohol Over Cu–Cr–Zn Mixed Oxide Catalysts Prepared by Utilizing Gamma Radiation
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Letters"
DOI: 10.1007/s10562-019-02815-6
Abstract: Selective hydrogenation of furfural to furfuryl alcohol was evaluated over Cu–Cr–Zn mixed oxide catalysts prepared by conventional and gamma radiation methods. The catalysts were characterized by different techniques. The variations in surface-structural properties of the… read more here.
Keywords: selective hydrogenation; catalysts prepared; gamma radiation;
Effect of Polyethylene Glycol on the Structure and Catalytic Properties of 1% Pd/ZnO Nanocomposites in the Selective Hydrogenation of Acetylenic Alcohols
Sign Up to like & getrecommendations! Published in 2018 at "Theoretical and Experimental Chemistry"
DOI: 10.1007/s11237-018-9572-8
Abstract: It is shown that modification of zinc oxide with polyethylene glycol leads to an increase in the catalytic activity of 1% Pd/ZnO nanocomposites in the low-temperature selective hydrogenation of acetylenic alcohols. This effect is due… read more here.
Keywords: zno nanocomposites; selective hydrogenation; acetylenic alcohols; hydrogenation acetylenic ... See more keywords
Selective hydrogenation of N-heterocyclic compounds over rhodium-copper bimetallic nanocrystals under ambient conditions
Sign Up to like & getrecommendations! Published in 2019 at "Nano Research"
DOI: 10.1007/s12274-019-2411-y
Abstract: Bimetallic nanocrystals (BMNCs) with distinguished electronic and chemical properties from those of their parent metals, offer the opportunity to obtain new catalysts with enhanced selectivity, activity, and stability. Here we describe the facile synthesis of… read more here.
Keywords: bimetallic nanocrystals; rhodium copper; selective hydrogenation; copper bimetallic ... See more keywords
Kinetics of phenylacetylene selective hydrogenation to styrene over metal-free polymeric carbon nitrides
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2018.07.033
Abstract: Abstract Hydrogenation of carbon–carbon multiple bonds is one of the most important processes widely used in chemical synthesis. We have shown for the first time that graphite-like carbon nitrides are capable of activating hydrogen molecules… read more here.
Keywords: carbon; hydrogenation; selective hydrogenation; kinetics phenylacetylene ... See more keywords
Ni nanoparticles entrapped in nickel phyllosilicate for selective hydrogenation of guaiacol to 2-methoxycyclohexanol
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2018.10.009
Abstract: Abstract Selective hydrogenation of guaiacol to valuable chemicals is especially attractive for the upgrading of lignin-derived platform compounds. However, the synthesis of 2-methoxycyclohexanol over non-noble metal catalyst is a great challenge under mild condition. In… read more here.
Keywords: hydrogenation; selective hydrogenation; nickel phyllosilicate; hydrogenation guaiacol ... See more keywords