Effect of tungsten species on selective hydrogenolysis of glycerol to 1,3-propanediol.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202002405
Abstract: Glycerol, as the major byproduct of biodiesel industry, is a cheap and green chemical feedstock. Following the expanded production of biodiesel, the oversupply of glycerol has led to the increasing researches of the catalytic conversion… read more here.
Keywords: selective hydrogenolysis; hydrogenolysis glycerol; glycerol propanediol; glycerol ... See more keywords
Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200092
Abstract: 2-Hexanol (2-HOL) is a versatile biomass-derived platform molecule for synthesis of liquid transportation fuels, lubricants or detergents. Herein, a one-step preparation of 2-HOL using 5-hydroxymethylfurfural (HMF) as a substrate was reported for the first time.… read more here.
Keywords: zro2 catalyst; hexanol; hydrogenolysis hydroxymethylfurfural; selective hydrogenolysis ... See more keywords
Investigation of the mechanism of the selective hydrogenolysis of C O bonds over a Pt/WO3/Al2O3 catalyst
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Today"
DOI: 10.1016/j.cattod.2019.10.008
Abstract: Abstract The hydrogenolysis of various polyols and ethers over a Pt/WO3/Al2O3 catalyst was investigated. The hydrogenolysis rate of a C O bond at a secondary carbon was higher than that at a primary carbon, indicating… read more here.
Keywords: al2o3 catalyst; selective hydrogenolysis; wo3 al2o3; bond ... See more keywords
Interface synergy between IrOx and H-ZSM-5 in selective C–O hydrogenolysis of glycerol toward 1,3-propanediol
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.06.025
Abstract: Abstract Site-selective deoxygenation of hydroxyl groups represents essential processes to access valuable functionalized bio-based compounds with industrial potential. One of the challenging tasks in this context is to convert biodiesel-derived glycerol in the presence of… read more here.
Keywords: selective hydrogenolysis; glycerol toward; hydrogenolysis glycerol; hydrogenolysis ... See more keywords
Highly active Cu-Zn-Mg-Al-O catalyst derived from layered double hydroxides (LDHs) precursor for selective hydrogenolysis of glycerol to 1,2-propanediol
Sign Up to like & getrecommendations! Published in 2017 at "Journal of environmental chemical engineering"
DOI: 10.1016/j.jece.2017.10.034
Abstract: Abstract Selective hydrogenolysis of glycerol to 1,2-propanediol (1,2-PDO) was performed by using environmentally friendly bifunctional layered double hydroxide (LDHs) type Cu-Mg-Al-O and Cu-Zn-Mg-Al-O catalysts prepared by urea hydrolysis method. The physicochemical properties of these catalysts… read more here.
Keywords: pdo; selective hydrogenolysis; hydrogenolysis glycerol; glycerol ... See more keywords
Selective Hydrogenolysis and Hydrogenation of Furfuryl Alcohol in the Aqueous Phase Using Ru–Mn-Based Catalysts
Sign Up to like & getrecommendations! Published in 2020 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.0c01023
Abstract: Most biomass derivatives were converted in the aqueous phase due to their high oxygen content, which, however, created a harsh environment for the catalytic reaction. In this work, Ru-based catalys... read more here.
Keywords: hydrogenation furfuryl; phase; aqueous phase; selective hydrogenolysis ... See more keywords
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over Rhenium-Oxide-Modified Iridium Nanoparticles Coating Rutile Titania Support
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03824
Abstract: The effect of support in Ir-ReOx catalysts for glycerol hydrogenolysis to 1,3-propanediol was investigated. Rutile TiO2 support showed high activity, even higher than previously reported SiO2 suppo... read more here.
Keywords: selective hydrogenolysis; hydrogenolysis glycerol; hydrogenolysis; rutile ... See more keywords
The selective hydrogenolysis of C-O bonds in lignin model compounds by Pd-Ni bimetallic nanoparticles in ionic liquids.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt02498c
Abstract: β-O-4 and α-O-4 linkages can be selectively cleaved by Pd-Ni bimetallic nanoparticles in ionic liquids using hydrogen gas as the hydrogen donor under ambient pressure and neutral conditions. No hydrogenation of the benzene ring takes… read more here.
Keywords: selective hydrogenolysis; nanoparticles ionic; bimetallic nanoparticles; bonds lignin ... See more keywords
New catalyst with multiple active sites for selective hydrogenolysis of cellulose to ethylene glycol
Sign Up to like & getrecommendations! Published in 2017 at "Green Chemistry"
DOI: 10.1039/c7gc02122d
Abstract: Three different metals were successfully incorporated into the mesoporous siliceous material, TUD-1, for the first time. One-pot synthesis was applied to incorporate isolated Al3+, nanoparticles of WO3, and nanoparticles of metallic Ni with different loadings… read more here.
Keywords: ethylene; selective hydrogenolysis; hydrogenolysis cellulose; catalyst multiple ... See more keywords