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Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc06210g
Abstract: para-Selective hydroxylation of alkyl aryl ethers is established, which proceeds with a ruthenium(II) catalyst, hypervalent iodine(III) and trifluoroacetic anhydride via a radical mechanism. This protocol tolerates a wide scope of substrates and provides a facile…
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Keywords:
aryl ethers;
hydroxylation alkyl;
para selective;
selective hydroxylation ... See more keywords
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Published in 2018 at "Journal of Porphyrins and Phthalocyanines"
DOI: 10.1142/s108842461850061x
Abstract: We herein report the H2O2-dependent selective hydroxylation of naphthalene catalyzed by engineered P450BM3 with the assistance of dual-functional small molecules (DFSMs). The mutation at position 268 significantly improved the hydroxylation activity of P450BM3, which is…
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Keywords:
hydroxylation;
h2o2 dependent;
dual functional;
engineered p450bm3 ... See more keywords