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Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.6b00816
Abstract: The five-coordinate iron(II) hydride complex (iPrPNP)Fe(H)CO (iPrPNP = N[CH2CH2(PiPr2)]2) was found to selectively catalyze deaminative hydrogenation of amides to the corresponding amines and primary alcohols. It is one of the most active amide hydrogenation catalysts…
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Keywords:
hydrogenation;
hydrogenation amides;
iron catalyzed;
deaminative hydrogenation ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b03542
Abstract: Single-electron oxidation and α-deprotonation of tertiary anilines using Fe(phen)3(PF6)3 afford α-aminoalkyl radicals, which can be coupled with electrophilic partners to afford various tetrahydroquinolines. Mechanistically, the Fe(phen)n2+/3+ catalytic cycle is maintained by O2 or a TBHP…
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Keywords:
iron catalysis;
oxidation;
redox selective;
iron ... See more keywords
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Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.9b00127
Abstract: Renewable phenols have been investigated as nucleophiles for the addition to a cationic cyclohexadienyl iron carbonyl scaffold. Benign conditions compatible with solvents such as ethanol and water were developed, and for the first time, selective…
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Keywords:
addition;
mediated addition;
selective iron;
addition phenolic ... See more keywords