Selective Light-Driven Chemoenzymatic Trifluoromethylation/Hydroxylation of Substituted Arenes
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DOI: 10.1021/acscatal.7b04160
Abstract: The merging of photoredox trifluoromethylation with hybrid P450 BM3 variants has enabled the selective light-driven functionalization of several arenes. This approach capitalizes on the unique photochemical properties of the Ru(II)-diimine photosensitizer to initiate single electron… read more here.
Keywords: selective light; light driven; chemoenzymatic trifluoromethylation; driven chemoenzymatic ... See more keywords
Cyclometalated platinum(II) complex as a selective light switch for G-quadruplex DNA.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt01188g
Abstract: Cyclometalated 1,3-bis(8-quinolyl) phenyl chloroplatinum(II) (Pt1) shows selective luminescence transduction of G-quadruplex binding over duplex DNA. The effect is enhanced on association with parallel and hybrid G-quadruplex structures over other topologies. The kinetics of binding are… read more here.
Keywords: dna; light switch; platinum complex; selective light ... See more keywords