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Published in 2018 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.08.017
Abstract: Abstract Four MIL metal organic framework materials with large surface area and high stability were utilized as heterogeneous catalysts in the selective oxidation of styrene with tert-butylhydroperoxide (70% aqueous) as an oxidant in acetonitrile. Mn-MIL-100…
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Keywords:
oxidative cleavage;
catalyst selective;
100 heterogeneous;
mil 100 ... See more keywords
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Published in 2020 at "Catalysis Today"
DOI: 10.1016/j.cattod.2019.05.002
Abstract: Abstract The oxidative upgrading of renewable furfural (FUR) and ethanol is an important way to produce high-quality liquid fuel and value-added furanic derivatives. In this work, a series of supported Au catalysts were prepared using…
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Keywords:
ethanol;
selective oxidative;
catalyst;
oxidative valorization ... See more keywords
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Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.03.094
Abstract: Abstract The single-step synthesis of protected fucols and unnatural polyaryls by biomimetic oxidative cross-coupling between phenolic components and 1,3,5-trimethoxybenzene catalyzed by FeCl3 in fluorinated solvents is reported. The regioselectivity (ortho, meta or para) and the…
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Keywords:
oxidative arylation;
catalyzed selective;
arylation phenols;
iron catalyzed ... See more keywords
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Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.2c04242
Abstract: A selective oxidative coupling reaction of a diamine containing both C- and N-NH2 was achieved using acidic potassium permanganate as the coupling reagent. The reaction conditions were optimized, and the reaction selectivity was illustrated by…
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Keywords:
site selective;
reaction;
coupling reaction;
reaction diamines ... See more keywords
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Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03476
Abstract: Catalytic methods for the site-selective scission of C(sp3)–C(sp3) bonds remain scarcely explored in contrast to the vast literature on C–C coupling. In view of this, we report a means of oxidative...
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Keywords:
catalysts selective;
bimetallic cobalt;
improved bimetallic;
manganese catalysts ... See more keywords
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Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01464
Abstract: This method afforded aromatic carbonyl compounds under TBHP via selective oxidative cleavage of the C–C bond in α,β-epoxy ketones. Aromatic acid came from the aroyl section, and aromatic aldehyde came from the other aromatic group.…
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Keywords:
cleavage;
carbonyl compounds;
cleavage bond;
selective oxidative ... See more keywords
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Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b00643
Abstract: A series of pyridine-type ligands containing C≡C bonds were designed and synthesized for selective oxidative Heck reaction. These ligands were utilized as functional units and integrated into the skeleton of conjugated microporous polymers. 6,6'-diiodo-2,2'-bipyridine and…
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Keywords:
ligand;
heck reaction;
oxidative heck;
selective oxidative ... See more keywords
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Published in 2021 at "Scientific Reports"
DOI: 10.1038/s41598-021-83863-0
Abstract: Herein, we present an interesting role of tungstate-decorated amphiphilic carbon quantum dots (A-CQDs/W) in the selective oxidative cleavage of alkenes to aldehydes. In this work, for the first time, we disclose an unprecedented tungstate-based oxidative…
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Keywords:
decorated amphiphilic;
catalyst;
tungstate;
amphiphilic carbon ... See more keywords
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Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c6qo00730a
Abstract: A highly site-selective oxidative C–H sulfonylation method for 8-acylaminoquinolines and anilides with sulfonyl chlorides has been developed, which provided C5-sulfonylated quinolines and para-sulfonylated anilides respectively. Good functional group compatibility was showed in both amides and…
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Keywords:
site selective;
selective oxidative;
oxidative sulfonylation;
acylaminoquinolines anilides ... See more keywords
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Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00623k
Abstract: Phenoxy radicals were converted intoparasite selectiveC-aryl radicals and coupled with quinones, using an inexpensive FeCl3–K2S2O8system, to obtain several arylated quinones, in good to moderate yields.
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Keywords:
aryl radicals;
selective oxidative;
site selective;
arylated quinones ... See more keywords
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Published in 2021 at "Green Chemistry"
DOI: 10.1039/d1gc00743b
Abstract: By introducing a polar atom at the γ-position of amine, the site-selective oxidative cleavage of the saturated C–C single bond in arylamines can be easily achieved by simple visible light irradiation with O2 as a benign…
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Keywords:
cleavage;
free photoinduced;
selective oxidative;
sp3 ... See more keywords