Mn-MIL-100 heterogeneous catalyst for the selective oxidative cleavage of alkenes to aldehydes
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.08.017
Abstract: Abstract Four MIL metal organic framework materials with large surface area and high stability were utilized as heterogeneous catalysts in the selective oxidation of styrene with tert-butylhydroperoxide (70% aqueous) as an oxidant in acetonitrile. Mn-MIL-100… read more here.
Keywords: oxidative cleavage; catalyst selective; 100 heterogeneous; mil 100 ... See more keywords
A selective oxidative valorization of biomass-derived furfural and ethanol with the supported gold catalysts
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Today"
DOI: 10.1016/j.cattod.2019.05.002
Abstract: Abstract The oxidative upgrading of renewable furfural (FUR) and ethanol is an important way to produce high-quality liquid fuel and value-added furanic derivatives. In this work, a series of supported Au catalysts were prepared using… read more here.
Keywords: ethanol; selective oxidative; catalyst; oxidative valorization ... See more keywords
Iron-catalyzed selective oxidative arylation of phenols and biphenols
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.03.094
Abstract: Abstract The single-step synthesis of protected fucols and unnatural polyaryls by biomimetic oxidative cross-coupling between phenolic components and 1,3,5-trimethoxybenzene catalyzed by FeCl3 in fluorinated solvents is reported. The regioselectivity (ortho, meta or para) and the… read more here.
Keywords: oxidative arylation; catalyzed selective; arylation phenols; iron catalyzed ... See more keywords
Site-Selective Oxidative Coupling Reaction of Diamines toward Aminoazo Compounds.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.2c04242
Abstract: A selective oxidative coupling reaction of a diamine containing both C- and N-NH2 was achieved using acidic potassium permanganate as the coupling reagent. The reaction conditions were optimized, and the reaction selectivity was illustrated by… read more here.
Keywords: site selective; reaction; coupling reaction; reaction diamines ... See more keywords
Improved Bimetallic Cobalt–Manganese Catalysts for Selective Oxidative Cleavage of Morpholine Derivatives
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03476
Abstract: Catalytic methods for the site-selective scission of C(sp3)–C(sp3) bonds remain scarcely explored in contrast to the vast literature on C–C coupling. In view of this, we report a means of oxidative... read more here.
Keywords: catalysts selective; bimetallic cobalt; improved bimetallic; manganese catalysts ... See more keywords
Selective Oxidative Cleavage of the C–C Bond in α,β-Epoxy Ketone into Carbonyl Compounds
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01464
Abstract: This method afforded aromatic carbonyl compounds under TBHP via selective oxidative cleavage of the C–C bond in α,β-epoxy ketones. Aromatic acid came from the aroyl section, and aromatic aldehyde came from the other aromatic group.… read more here.
Keywords: cleavage; carbonyl compounds; cleavage bond; selective oxidative ... See more keywords
Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b00643
Abstract: A series of pyridine-type ligands containing C≡C bonds were designed and synthesized for selective oxidative Heck reaction. These ligands were utilized as functional units and integrated into the skeleton of conjugated microporous polymers. 6,6'-diiodo-2,2'-bipyridine and… read more here.
Keywords: ligand; heck reaction; oxidative heck; selective oxidative ... See more keywords
Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
Sign Up to like & getrecommendations! Published in 2021 at "Scientific Reports"
DOI: 10.1038/s41598-021-83863-0
Abstract: Herein, we present an interesting role of tungstate-decorated amphiphilic carbon quantum dots (A-CQDs/W) in the selective oxidative cleavage of alkenes to aldehydes. In this work, for the first time, we disclose an unprecedented tungstate-based oxidative… read more here.
Keywords: decorated amphiphilic; catalyst; tungstate; amphiphilic carbon ... See more keywords
Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions
Sign Up to like & getrecommendations! Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c6qo00730a
Abstract: A highly site-selective oxidative C–H sulfonylation method for 8-acylaminoquinolines and anilides with sulfonyl chlorides has been developed, which provided C5-sulfonylated quinolines and para-sulfonylated anilides respectively. Good functional group compatibility was showed in both amides and… read more here.
Keywords: site selective; selective oxidative; oxidative sulfonylation; acylaminoquinolines anilides ... See more keywords
Iron-mediated site-selective oxidative C–H/C–H cross-coupling of aryl radicals with quinones: synthesis of β-secretase-1 inhibitor B and related arylated quinones
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00623k
Abstract: Phenoxy radicals were converted intoparasite selectiveC-aryl radicals and coupled with quinones, using an inexpensive FeCl3–K2S2O8system, to obtain several arylated quinones, in good to moderate yields. read more here.
Keywords: aryl radicals; selective oxidative; site selective; arylated quinones ... See more keywords
Catalyst-free photoinduced selective oxidative C(sp3)–C(sp3) bond cleavage in arylamines
Sign Up to like & getrecommendations! Published in 2021 at "Green Chemistry"
DOI: 10.1039/d1gc00743b
Abstract: By introducing a polar atom at the γ-position of amine, the site-selective oxidative cleavage of the saturated C–C single bond in arylamines can be easily achieved by simple visible light irradiation with O2 as a benign… read more here.
Keywords: cleavage; free photoinduced; selective oxidative; sp3 ... See more keywords