Immobilization of Mn(i) and Ru(ii) polypyridyl complexes on TiO2 nanoparticles for selective photoreduction of CO2 to formic acid.
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DOI: 10.1039/c9cc05129e
Abstract: TiO2 nanoparticles are successively functionalized with [Mn(κ2N1,N2-ttpy)(CO)3Br] as catalyst and [Ru(bpy)3]2+ as photosensitizer to yield RuII/TiO2/MnI. Under continuous irradiation at 470 nm and in the presence of a sacrificial electron donor, this triad reduces CO2… read more here.
Keywords: nanoparticles selective; selective photoreduction; complexes tio2; immobilization polypyridyl ... See more keywords