Helix-Sense-Selective Polymerization of Achiral Monomers for the Preparation of Chiral Helical Polyacetylenes Showing Intense CPL in Solid Film State.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200111
Abstract: Polymer-based circularly polarized luminescent (CPL) materials have attracted ever-increasing interests. However, how to construct CPL materials from achiral monomers is still a big challenge. Here, a series of chiral helical substituted polyacetylenes are prepared by… read more here.
Keywords: chiral helical; achiral monomers; selective polymerization; sense selective ... See more keywords
The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review
Sign Up to like & getrecommendations! Published in 2023 at "Polymers"
DOI: 10.3390/polym15051105
Abstract: In this review, all available publications on the polymerization of all isomers of bifunctional diethynylarenes due to the opening of C≡C bonds were considered and analyzed. It has been shown that with the use of… read more here.
Keywords: review; polymerization one; polymerization; polymers diethynylarenes ... See more keywords