Selective Radical Trifluoromethylation of Native Residues in Proteins
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DOI: 10.1021/jacs.7b10230
Abstract: The incorporation of fluorine can not only significantly facilitate the study of proteins but also potentially modulate their function. Though some biosynthetic methods allow global residue-replacement, post-translational fluorine incorporation would constitute a fast and efficient… read more here.
Keywords: selective radical; trifluoromethylation; residues proteins; radical trifluoromethylation ... See more keywords
Selective radical cascade (4+2) annulation with olefins towards the synthesis of chroman derivatives via organo-photoredox catalysis
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DOI: 10.1039/d2sc00903j
Abstract: Due to the importance of chroman frameworks in medicinal chemistry, the development of novel synthetic methods for these structures is gaining increasing interest of chemists. Reported here is a new (4 + 2) radical annulation… read more here.
Keywords: annulation olefins; cascade annulation; annulation; radical cascade ... See more keywords
In Situ Prepared Solar Light‐Driven Flexible Actuated Carbon Cloth‐Based Nanorod Photocatalyst for Selective Radical–Radical Coupling to Vinyl Sulfides
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DOI: 10.1111/php.13412
Abstract: A global challenge faced by light harvesting photocatalyst is how to promote the selective organic transformation, such as C‐S bond formation via radical–radical coupling under solar light. Here, we report a two‐dimensional covalent organic frameworks… read more here.
Keywords: radical radical; selective radical; solar light; photocatalyst ... See more keywords