Photoredox Ni-Catalyzed Branch-Selective Reductive Coupling of Aldehydes with 1,3-Dienes
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DOI: 10.1021/acscatal.9b05137
Abstract: We report here a Ni-catalyzed reductive coupling of aldehydes with widely available 1,3-dienes under visible-light photoredox dual catalysis. The homoallyic alcohols are obtained in broad scope with complete branched regioselectivity. Hantzsch ester is used as… read more here.
Keywords: coupling aldehydes; catalyzed branch; branch selective; selective reductive ... See more keywords
Exo-selective, Reductive Heck Derived Polynorbornenes with Enhanced Molecular Weights, Yields, and Hydrocarbon Gas Transport Properties
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DOI: 10.1021/acsmacrolett.0c00555
Abstract: Next-generation membranes use highly engineered polymeric structures with enhanced chain rigidity, yet difficulties in polymerization often limit molecular weights required for film formation. Addi... read more here.
Keywords: molecular weights; reductive heck; heck derived; derived polynorbornenes ... See more keywords