(NHC-olefin)-nickel(0) nanoparticles as catalysts for the (Z)-selective semi-hydrogenation of alkynes and ynamides.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc05302k
Abstract: Nickel(0) nanoparticles coordinated to NHC ligands bearing N-coordinated cinnamyl moieties were readily prepared by reduction of a [NiCpBr(NHC-cinnamyl)] complex with methyl magnesium bromide. The combination of a strong σ-donor NHC ligand with a π-coordinating appended… read more here.
Keywords: semi hydrogenation; selective semi; nickel nanoparticles; alkynes ynamides ... See more keywords
Synthetic Strategies of Supported Pd-Based Bimetallic Catalysts for Selective Semi-Hydrogenation of Acetylene: A Review and Perspectives
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DOI: 10.3390/molecules28062572
Abstract: Selective semi-hydrogenation of acetylene is an extremely important reaction from both industrial and theoretical perspectives. Palladium, due to its unique chemical and physical properties, is the most active and currently irreplaceable metal for this reaction… read more here.
Keywords: semi hydrogenation; selective semi; supported based; hydrogenation acetylene ... See more keywords