Highly Selective Transformation of Biomass Derivatives to Valuable Chemicals by Single‐Atom Photocatalyst Ni/TiO2
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202209646
Abstract: Selective CC cleavage of the biomass derivative glycerol under mild conditions is recognized as a promising yet challenging synthesis route to produce value‐added chemicals. Here, a highly selective catalyst for the transformation of glycerol to… read more here.
Keywords: photocatalyst; single atom; biomass; highly selective ... See more keywords
Critical Factors Affecting the Selective Transformation of 5‐Hydroxymethylfurfural to 3‐Hydroxymethylcyclopentanone Over Ni Catalysts
Sign Up to like & getrecommendations! Published in 2024 at "Chemsuschem"
DOI: 10.1002/cssc.202400559
Abstract: Abstract The ring‐rearrangement of 5‐hydroxymethylfurfural (HMF) to 3‐hydroxymethylcyclopentanone (HCPN) was investigated over Ni catalysts supported on different carbon supports and metallic oxides with different structure and acid‐base properties. Their catalytic performance was tested in a… read more here.
Keywords: hydroxymethylcyclopentanone; factors affecting; transformation hydroxymethylfurfural; affecting selective ... See more keywords
Tunable and selective transformation of aromatic thioether enabled by regulating active species under visible light irradiation
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202401092
Abstract: Through effective regulation of active species in photocatalytic process, the oxidation or C(sp3)‐S bond cleavage upgrading of widespread aryl alkyl sulfides under mild conditions was successfully achieved by using a pyridinium photocatalyst. Benefiting from the… read more here.
Keywords: visible light; tunable selective; selective transformation; active species ... See more keywords
Insights into the Selective Transformation of Ceria Sulfation and Iron/Manganese Mineralization for Enhancing the Selective Recovery of Rare Earth Elements.
Sign Up to like & getrecommendations! Published in 2023 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c08395
Abstract: To cope with the urgent and unprecedented demands for rare earth elements (REEs) in sophisticated industries, increased attention has been paid to REE recovery from recycled streams. However, the similar geochemical behaviors of REEs and… read more here.
Keywords: earth elements; rare earth; selective transformation; transformation ... See more keywords
Selective Transformation of Micropollutants in Saline Wastewater by Peracetic Acid: The Overlooked Brominating Agents.
Sign Up to like & getrecommendations! Published in 2023 at "Environmental science & technology"
DOI: 10.1021/acs.est.3c00835
Abstract: Peracetic acid (PAA) is an emerging alternative disinfectant for saline waters; HOBr or HOCl is known as the sole species contributing to halogenation reactions during PAA oxidation and disinfection. However, new results herein strongly indicated… read more here.
Keywords: peracetic acid; brominating agents; overlooked brominating; transformation ... See more keywords
A study on selective transformation of norbornadiene into fluorinated cyclopentane-fused isoxazolines
Sign Up to like & getrecommendations! Published in 2021 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.17.132
Abstract: This work presents an examination of the selective functionalization of norbornadiene through nitrile oxide 1,3-dipolar cycloaddition/ring-opening metathesis (ROM)/cross-metathesis (CM) protocols. Functionalization of commercially available norbornadiene provided novel bicyclic scaffolds with multiple stereogenic centers. The synthesis… read more here.
Keywords: transformation norbornadiene; selective transformation; norbornadiene fluorinated; study selective ... See more keywords