Selective Vinylogous Reactivity of Carbene Intermediate in Gold-Catalyzed Alkyne Carbocyclization: Synthesis of Indenols
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DOI: 10.1021/acscatal.8b04144
Abstract: A gold-catalyzed carbocyclization of alkynes with a pendant diazo group that is completed by reaction with a protic nucleophile for the synthesis of indenol derivatives with a tertiary center is described. Mechanistic studies and DFT… read more here.
Keywords: selective vinylogous; synthesis; gold catalyzed; carbocyclization ... See more keywords