Breaking Trade‐Off between Selectivity and Activity of Nickel‐Based Hydrogenation Catalysts by Tuning Both Steric Effect and d‐Band Center
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DOI: 10.1002/advs.201900054
Abstract: Abstract For selective hydrogenation of chemicals the high selectivity is always at the expense of activity and improving both selectivity and activity is challenging. Here, by chelating with p‐fluorothiophenol (SPhF)‐arrays, both steric and electronic effects… read more here.
Keywords: nickel based; hydrogenation; selectivity activity; band center ... See more keywords
Achieving Tunable Selectivity and Activity of CO2 Electroreduction to CO via Bimetallic Silver-Copper Electronic Engineering.
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DOI: 10.1002/smll.202207242
Abstract: Limited comprehension of the reaction mechanism has hindered the development of catalysts for CO2 reduction reactions (CO2 RR). Here, the bimetallic AgCu nanocatalyst platform is employed to understand the effect of the electronic structure of… read more here.
Keywords: selectivity activity; co2 electroreduction; selectivity; activity co2 ... See more keywords