Selectivity Control for Cellulose to Diols: Dancing on Eggs
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DOI: 10.1021/acscatal.6b03469
Abstract: Catalytic conversion of cellulose to ethylene glycol (EG) or 1,2-propylene glycol (1,2-PG) represents an attractive approach in the valorization of biomass, due to the high atom economy of the reaction process and large market demand… read more here.
Keywords: control cellulose; selectivity control; reaction; selectivity ... See more keywords
H-Bond-Mediated Selectivity Control of Formate versus CO during CO2 Photoreduction with Two Cooperative Cu/X Sites.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c13048
Abstract: It is highly desirable to achieve solar-driven conversion of CO2 to valuable fuels with controlled selectivity. The existing catalysts are mainly explored for CO production but rarely for formate generation. Herein, highly selective photoreduction of… read more here.
Keywords: bond; co2 photoreduction; photoreduction; selectivity control ... See more keywords
Strategies That Utilize Ion Pairing Interactions to Exert Selectivity Control in the Functionalization of C–H Bonds
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08752
Abstract: Electrostatic attraction between two groups of opposite charge, typically known as ion-pairing, offers unique opportunities for the design of systems to enable selectivity control in chemical reactions. Catalysis using noncovalent interactions is an established and… read more here.
Keywords: pairing interactions; ion pairing; control; selectivity ... See more keywords