Selectivity Switch in the Aerobic 1,2‐Propandiol Oxidation Catalyzed by Diamine‐Stabilized Palladium Nanoparticles
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DOI: 10.1002/cctc.202100309
Abstract: Palladium nanoparticles stabilized by a sterically demanding secondary diamine ligand have been synthesized by hydrogen reduction of a palladium acetate complex bearing the corresponding diimine ligand. The obtained nanoparticles were used to catalyze the aerobic… read more here.
Keywords: palladium nanoparticles; oxidation; selectivity switch; diamine ... See more keywords
On-Water Selectivity Switch in Microdroplets in the 1,2,3-Triazole Synthesis from Bromoethenesulfonyl Fluoride.
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DOI: 10.1021/jacs.1c08879
Abstract: Water profoundly affects many organic reactions by accelerating them or changing their selectivity. Performing reactions "on-water" offers an intriguing opportunity to influence chemical reactivity. A nebulizer plume is an efficient way of generating microdroplets-the uniquely… read more here.
Keywords: water; microdroplets triazole; selectivity switch; switch microdroplets ... See more keywords
Selectivity switch by phase switch – the key to a high-yield furfural process
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DOI: 10.1039/d1gc01752g
Abstract: A transient monophasic system, with an aromatic solvent, a polar organic solvent, acidic water and PBA, is used to convert xylose into furfural with a selectivity >90 mol%. and its integration into a process concept… read more here.
Keywords: phase switch; switch phase; selectivity switch; process ... See more keywords