Modeling the Catalytic Cycle of Glutathione Peroxidase by Nuclear Magnetic Resonance Spectroscopic Analysis of Selenocysteine Selenenic Acids.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c02383
Abstract: Although selenocysteine selenenic acids (Sec-SeOHs) have been recognized as key intermediates in the catalytic cycle of glutathione peroxidase (GPx), examples of the direct observation of Sec-SeOH in either protein or small-molecule systems have remained elusive… read more here.
Keywords: cycle glutathione; selenenic acids; selenocysteine selenenic; glutathione peroxidase ... See more keywords
Model study on trapping of protein selenenic acids by utilizing a stable synthetic congener
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj01072f
Abstract: Model studies on the trapping reaction of protein selenenic acids were carried out with a stable primary-alkyl model compound. read more here.
Keywords: model study; model; protein selenenic; study trapping ... See more keywords