Modeling the Catalytic Cycle of Glutathione Peroxidase by Nuclear Magnetic Resonance Spectroscopic Analysis of Selenocysteine Selenenic Acids.
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DOI: 10.1021/jacs.1c02383
Abstract: Although selenocysteine selenenic acids (Sec-SeOHs) have been recognized as key intermediates in the catalytic cycle of glutathione peroxidase (GPx), examples of the direct observation of Sec-SeOH in either protein or small-molecule systems have remained elusive… read more here.
Keywords: cycle glutathione; selenenic acids; selenocysteine selenenic; glutathione peroxidase ... See more keywords