Self-Accelerating Click Reaction in Step Polymerization
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01173
Abstract: A self-accelerating double-strain-promoted azide–alkyne cycloaddition reaction (DSPAAC) was used in the step polymerization for the first time. This produced a novel stoichiometric imbalance-promoted homogeneous step polymerization method using sym-dibenzo-1,5-cyclooctadiene-3,7-diyne (DIBOD) and various bis-azide compounds (N3-R-N3)… read more here.
Keywords: polymerization; step polymerization; self accelerating; reaction ... See more keywords
Ultramicroporous Organophosphorus Polymers via Self-Accelerating P-C Coupling Reactions: Kinetic Effects on Crosslinking Environments and Porous Structures.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03759
Abstract: Porous organic polymers (POPs) have drawn significant attention in diverse applications. However, factors affecting the heterogeneous polymerization and porosity of POPs are still not well understood. Herein, we report a new strategy to construct porous… read more here.
Keywords: crosslinking environments; reaction; coupling reaction; self accelerating ... See more keywords
A dual-amplified ROS-responsive nanosystem with self-accelerating drug release for synergistic chemotherapy.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00052d
Abstract: In this work, we have developed a tumor-specific self-accelerating prodrug activation nanosystem consisting of self-amplifying degradable polyprodrug PEG-TA-CA-DOX and encapsulated fluorescent prodrug BCyNH2, equipped with a reactive oxygen species dual-cycle amplification effect. Furthermore, activated CyNH2… read more here.
Keywords: dual amplified; amplified ros; self accelerating; ros responsive ... See more keywords