Self-condensing reversible complexation-mediated copolymerization for highly branched polymers with in situ formed inimers
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py01560g
Abstract: In this work, reversible complexation-mediated polymerization (RCMP) was modified to suit self-condensing vinyl polymerization (SCVP) aimed at the synthesis of highly branched polymers. For this purpose, two azo-containing pre-inimers with divinyl (DMACPO) or monovinyl (MACPO)… read more here.
Keywords: complexation mediated; polymerization; self condensing; reversible complexation ... See more keywords
Facile synthesis and characterization of highly branched polystyrene by self-condensing atom transfer radical polymerization
Sign Up to like & getrecommendations! Published in 2017 at "Molecular Crystals and Liquid Crystals"
DOI: 10.1080/15421406.2018.1450827
Abstract: ABSTRACT To simply prepare hyperbranched polystyrene with dendritic structure for optical and electronic applications, the copper-mediated self-condensing atom transfer radical polymerization of 4-(2-bromopropionyl)oxy styrene has been attempted. Given the unequal reactivity of two propagating species… read more here.
Keywords: atom transfer; self condensing; polymerization; transfer radical ... See more keywords