Self-deoxygenating glassware.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03477c
Abstract: The removal of dissolved oxygen (O2) from solution is a prerequisite for many reactions, frequently requiring specialized equipment/reagents or expertise. Herein, we introduce a range of reusable, shelf-stable enzyme-functionalized glassware, which biocatalytically removes O2 from… read more here.
Keywords: deoxygenating glassware; self deoxygenating; glassware;
Rapidly self-deoxygenating controlled radical polymerization in water via in situ disproportionation of Cu(i)†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc01512a
Abstract: Rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(i)/Me6Tren in water towards Cu(ii) and highly reactive Cu(0) leads to O2-free reaction environments within the first seconds of the reaction, even when the… read more here.
Keywords: polymerization; water; self deoxygenating; rapidly self ... See more keywords