Redox tuning of the H-cluster by second coordination sphere amino acids in the sensory [FeFe] hydrogenase from Thermotoga maritima
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DOI: 10.1039/d2sc06432d
Abstract: [FeFe] hydrogenases are exceptionally active catalysts for the interconversion of molecular hydrogen with protons and electrons. Their active site, the H-cluster, is composed of a [4Fe–4S] cluster covalently linked to a unique [2Fe] subcluster. These… read more here.
Keywords: thermotoga maritima; coordination; redox; sensory fefe ... See more keywords