Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)
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DOI: 10.1016/j.jssc.2018.03.033
Abstract: Abstract Three new d10 transition metal selenites containing PO4 tetrahedron, namely, Cd7(HPO4)2(PO4)2(SeO3)2 (1), Cd6(PO4)1.34(SeO3)4.66 (2) and Zn3(HPO4)(SeO3)2(H2O) (3), have been synthesized by hydrothermal reaction. They feature three different structural types. Compound 1 exhibits a novel… read more here.
Keywords: po4 seo3; po4; new d10; three new ... See more keywords
Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations.
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DOI: 10.1021/acs.inorgchem.8b00305
Abstract: A series of lithium metal selenites, Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2, were synthesized by hydrothermal and solid-state reactions. Li6M(SeO3)4 is composed of Li+ cations, MO6 octahedra, and SeO3 polyhedra, while Li2Zn(SeO3)2… read more here.
Keywords: li6m seo3; transition; metal; li2zn seo3 ... See more keywords
First chiral fluorinated lead vanadate selenite Pb2(V2O4F)(VO2)(SeO3)3 with five asymmetric motifs and large optical properties.
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DOI: 10.1039/d1dt00536g
Abstract: The first fluorinated lead vanadate selenite Pb2(V2O4F)(VO2)(SeO3)3 (PVOFS) was successfully synthesized via a mild hydrothermal method. This compound crystallizes in the chiral space group P212121 of the orthorhombic system and it is the first noncentrosymmetric… read more here.
Keywords: lead vanadate; selenite pb2; pb2 v2o4f; fluorinated lead ... See more keywords