Positional Installation of Unsymmetrical Fluorine Functionalities onto Metal-Organic Frameworks for Efficient Carbon Dioxide Separation under Humid Conditions.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02496
Abstract: Unsymmetrical trifluoro functional groups were installed onto metal-organic frameworks (MOFs) at positions regulated by ligand exchange for efficient CO2 separation under humid conditions. These trifluoro groups induced molecular separation via dipole-dipole interactions. Their installation onto… read more here.
Keywords: onto metal; metal organic; separation; humid conditions ... See more keywords
Tuning the Pore Environment of MOFs toward Efficient CH4/N2 Separation under Humid Conditions.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c01156
Abstract: Adsorption separation technology using adsorbents is promising as an alternative to the energy-demanding cryogenic distillation of natural gas (CH4/N2) separation. Although a few adsorbents, such as metal-organic frameworks (MOFs), with high performance for CH4/N2 separation,… read more here.
Keywords: separation humid; ch4; dmof; humid conditions ... See more keywords