Charge-Separation-Type Ionic Crystals with Mixed AuI4CoIII2 and AuI4NiIICoIII Hexanuclear Complexes.
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DOI: 10.1021/acs.inorgchem.0c00872
Abstract: Treatment of a digold(I) metalloligand, [AuI2(dppe)(d-Hpen)2] (H2LAu; d-H2pen = d-penicillamine, dppe = 1,2-bis(diphenylphosphino)ethane), with a 1:1 mixture of Co(OAc)2 and Ni(OAc)2 under aerobic conditions resulted in the formation of three types of hexanuclear complexes: [CoIII2(LAu)2]2+,… read more here.
Keywords: hexanuclear complexes; charge; separation type; charge separation ... See more keywords