Controlling Rheology of Fluid Interfaces through Microblock Length of Sequence-Controlled Amphiphilic Copolymers.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular chemistry and physics"
DOI: 10.1002/macp.202200110
Abstract: Previous studies have demonstrated that films of sequence-controlled amphiphilic copolymers display contact angles that depend on microblock size. This suggests that microblock length may provide a means of tuning surface and interfacial properties. In this… read more here.
Keywords: sequence controlled; rheology; microblock length; controlled amphiphilic ... See more keywords
Sequence-Controlled Synthesis of Advanced Clickable Synthetic Oligonucleotides.
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202000327
Abstract: Through thiol-ene photopolymerization of presynthesized oligomers, advanced clickable nucleic acids (CNA-2G) are synthesized with sequence-controlled repeating units. As examples, poly(thymine-adenine) (polyTA) CNA-2G and poly(thymine-thymine-cytosine) CNA-2G are synthesized by polymerizing thiol-ene heterofunctional dimers with pendant thymine-adenine… read more here.
Keywords: growth propagation; thiol ene; sequence controlled; advanced clickable ... See more keywords
Development of Sequence-Controlled, Degradable, and Cytocompatible Oligomers with Explicit Fragmentation Pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200788
Abstract: Sequence-defined and degradable polymers can mimic biopolymers, such as peptides and DNA, to undertake life-supporting functions in a chemical way. The design and development of well-structured oligomers/polymers is the most concern for the public, even… read more here.
Keywords: sequence controlled; fragmentation; development; sequence ... See more keywords
A strategy combining quantitative reactions and reversible-covalent chemistry for sequential synthesis of sequence-controlled polymers with different sequences
Sign Up to like & getrecommendations! Published in 2019 at "Polymer"
DOI: 10.1016/j.polymer.2019.04.017
Abstract: Abstract A new strategy combing quantitative reactions and reversible-covalent chemistry is proposed for sequential synthesis of a series of sequence-controlled polymers with different sequences. Using a Michael addition reaction between acrylate and thiol, an aminolysis… read more here.
Keywords: synthesis; controlled polymers; strategy; sequence controlled ... See more keywords
Strategies for the synthesis of sequence-controlled glycopolymers and their potential for advanced applications
Sign Up to like & getrecommendations! Published in 2021 at "Progress in Polymer Science"
DOI: 10.1016/j.progpolymsci.2021.101393
Abstract: Abstract Natural and largely abundant macromolecules such as carbohydrates have become a center point of interest for the polymer community, mostly due to their more environment-friendly nature and excellent capacity to bind to proteins found… read more here.
Keywords: strategies synthesis; synthesis sequence; sequence controlled; controlled glycopolymers ... See more keywords
Revealing Data Encrypted in Sequence-Controlled Poly(Alkoxyamine Phosphodiester)s by Combining Ion Mobility with Tandem Mass Spectrometry.
Sign Up to like & getrecommendations! Published in 2019 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.9b00813
Abstract: The defined sequence of two comonomers in sequence-controlled macromolecules can be used to store binary information which is further decoded by MS/MS sequencing. In order to achieve the full sequence coverage requested for reliable decoding,… read more here.
Keywords: sequence controlled; ion mobility; poly alkoxyamine; sequence ... See more keywords
Sequence-Controlled Secondary Structures and Stimuli Responsiveness of Bioinspired Polyampholytes.
Sign Up to like & getrecommendations! Published in 2022 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.2c00666
Abstract: A comprehensive study focusing on the influence of the sequence charge pattern on the secondary structure preferences of annealed polyampholytes and their responsiveness to external stimuli is presented. Two sequences are designed composed entirely of… read more here.
Keywords: controlled secondary; secondary structures; sequence controlled; secondary structure ... See more keywords
Efficient Access to Sequence-Controlled Poly(α-hydroxy acids) with Ax(BC)yDz-Type and Ax(BC)yAz-Type Triblock Structures via Self-Switchable Ring-Opening Polymerization of Monomer Mixtures.
Sign Up to like & getrecommendations! Published in 2023 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.3c00211
Abstract: Synthesizing block-sequence-controlled poly(α-hydroxy acids) of three or four α-hydroxy acids remains challenging in one step. In this study, a strategy was employed using three monomers of O-carboxyanhydrides (OCAs) consisting of one α-hydroxy acid (A), asymmetric… read more here.
Keywords: sequence controlled; via self; sequence; hydroxy acids ... See more keywords
Metal-Free Multicomponent Tandem Polymerizations of Alkynes, Amines, and Formaldehyde toward Structure- and Sequence-Controlled Luminescent Polyheterocycles.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b12767
Abstract: Sequence-controlled polymers, including biopolymers such as DNA, RNA, and proteins, have attracted much attention recently because of their sequence-dependent functionalities. The development of an efficient synthetic approach for non-natural sequence-controlled polymers is hence of great… read more here.
Keywords: metal free; multicomponent tandem; sequence; sequence controlled ... See more keywords
Accelerated chemoselective reactions to sequence-controlled heterolayered dendrimers.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b11726
Abstract: Chemoselective reactions are a highly desirable approach to generate well-defined functional macromolecules. Their ex-traordinary efficiency and selectivity enable the development of flawless structures, such as dendrimers, with unprece-dented structure-to-property capacity but with typically tedious synthetic… read more here.
Keywords: chemoselective reactions; accelerated chemoselective; heterolayered dendrimers; controlled heterolayered ... See more keywords
Construction methodologies and sequence-oriented properties of sequence-controlled oligomers/polymers generated via radical polymerization
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Journal"
DOI: 10.1038/s41428-020-00405-7
Abstract: The chain-growth polymerization mechanism is essentially unsuitable for sequence control due to the statistical propagation feature. However, the development of reversible-deactivation radical polymerization (RDRP) has opened the door to sequence control for carbon–carbon bond-based synthetic… read more here.
Keywords: polymerization; radical polymerization; sequence controlled; controlled oligomers ... See more keywords