Temperature triggered alternating copolymerization of epoxides and lactones via pre-sequenced spiroorthoester intermediates
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DOI: 10.1039/d1sc06634j
Abstract: We report the alternating copolymerization of caprolactone and epoxide through the in situ formation of pre-sequenced spiroorthoester monomer. The reaction is catalyzed by the temperature triggered, bifunctional cationic indium complex (±)-[(NNiOtBu)In(CH2SiMe3)][B(C6F5)4] (1). 1 can catalyze… read more here.
Keywords: temperature triggered; pre sequenced; sequenced spiroorthoester; alternating copolymerization ... See more keywords