One‐Pot Solvent‐Free Synthesis of Diaryl 1,2‐Diketones by the Sequential Heck Oxidation Reaction of Aryl Halides with Styrenes
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DOI: 10.1002/ajoc.201600529
Abstract: A novel one-pot procedure for the synthesis of benzil derivatives was developed by the sequential Heck oxidation reaction of aryl halides (I and Br) with styrenes. In situ-generated stilbene scaffolds were directly converted to the… read more here.
Keywords: oxidation; diaryl diketones; reaction; one pot ... See more keywords
Pd-catalyzed intramolecular sequential Heck cyclization and oxidation reactions: a facile pathway for the synthesis of substituted cycloheptenone evaluated using computational studies
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DOI: 10.1039/c6nj02694j
Abstract: A simple and convenient method for the construction of substituted cycloheptenones from 1-bromoocta-1,7-diene-3-ols has been developed. The reaction involves Pd(0)-catalyzed intramolecular 7-exo-trig cyclization followed by Pd(II)-catalyzed oxidation of cyclic alcohol. The course of the reaction… read more here.
Keywords: oxidation; cyclization; intramolecular sequential; sequential heck ... See more keywords