Ruthenium-Catalyzed Sequential Hydrosilylation/Dehydrogenation and C-H Silylation: Synthesis of Six-Membered Indole Silacycles and Pyrrole Silyl Ether Cycles.
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DOI: 10.1021/acs.orglett.4c01949
Abstract: Selective dehydrogenative C-H silylation is one of the most powerful tools to synthesize silacycles. Herein, we developed Ru-catalyzed sequential hydrosilylation/C-H silylation of allyl-indoles and dehydrogenative O-H/C-H silylation of pyrrole phenols. Both six-membered indole silacycles and… read more here.
Keywords: catalyzed sequential; sequential hydrosilylation; membered indole; six membered ... See more keywords
Ligand relay catalysis for cobalt-catalyzed sequential hydrosilylation and hydrohydrazidation of terminal alkynes
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DOI: 10.1038/s41467-022-28285-w
Abstract: Sequential double hydrofunctionalizationalization of alkynes is a powerful method to construct useful vicinal compounds. Herein, we report a cobalt-catalyzed sequential hydrosilylation/hydrohydrazidation of alkynes to afford 1,2- N,Si compounds via ligand relay catalysis. A phenomenon of… read more here.
Keywords: sequential hydrosilylation; hydrosilylation hydrohydrazidation; cobalt catalyzed; relay catalysis ... See more keywords