A Random-Sequential Kinetic Mechanism for Polysaccharide Monooxygenases.
Sign Up to like & getrecommendations! Published in 2018 at "Biochemistry"
DOI: 10.1021/acs.biochem.8b00129
Abstract: Polysaccharide monooxygenases (PMOs) are mononuclear copper enzymes that catalyze the hydroxylation of polysaccharides leading to the scission of the glycosidic bond. The mechanism, in which PMOs utilize molecular oxygen to oxidize the polysaccharide substrate, still… read more here.
Keywords: mechanism; random sequential; polysaccharide; sequential kinetic ... See more keywords
One-Pot Sequential Kinetic Profiling of a Highly Reactive Manganese Catalyst for Ketone Hydroboration: Leveraging σ-Bond Metathesis via Alkoxide Exchange Steps.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b05340
Abstract: A comprehensive experimental and computational mechanistic study of the highly enantioselective hydroboration of ketones catalyzed by a manganese(II) alkyl boxmi pincer complex is reported. The catalyst operates at low catalyst loadings (down to 0.01 mol… read more here.
Keywords: sequential kinetic; one pot; bond metathesis; catalyst ... See more keywords