Sequential Oxidative and Reductive Radical Cyclization Approach toward Asperparaline C and Synthesis of Its 8-Oxo Analogue.
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DOI: 10.1021/acs.orglett.7b00187
Abstract: The most advanced approach, so far, to the asperparalines is developed. Consecutive oxidative and reductive radical cyclizations serve as the key steps to stereoselectively access the complex fully elaborated skeleton containing the cyclopentane and spiro-succinimide… read more here.
Keywords: sequential oxidative; cyclization approach; radical cyclization; reductive radical ... See more keywords