Assessing the Metal-Metal Interactions in a Series of Heterobimetallic Nb/M Complexes (M = Fe, Co, Ni, Cu) and Their Effect on Multielectron Redox Properties.
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DOI: 10.1021/acs.inorgchem.8b02960
Abstract: A one-pot synthetic procedure for a series of bimetallic Nb/M complexes, Cl-Nb( iPrNPPh2)3M-X (M = Fe (2), Ni (4), Cu (5)), is described. A similar procedure aimed at synthesizing a Nb/Co analogue instead affords iPrN═Nb(… read more here.
Keywords: metal; series heterobimetallic; metal interactions; metal metal ... See more keywords
Tunable Binding of Dinitrogen to a Series of Heterobimetallic Hydride Complexes
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DOI: 10.1021/acs.organomet.8b00340
Abstract: The reaction of [Ru(H)2(N2)2(PCy3)2] (1) with β-diketiminate stabilized hydrides of Al, Zn, and Mg generates a series of new heterobimetallic complexes with either H2 or N2 ligated to the ruthenium center. Changing the main-group fragment… read more here.
Keywords: heterobimetallic hydride; binding dinitrogen; series heterobimetallic; series ... See more keywords