Orbital control over the metal vs. ligand reduction in a series of neutral and cationic bis(cyclopentadienyl) Ti(IV) complexes
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DOI: 10.1039/c7nj03746e
Abstract: Quantum chemistry calculations showed that the first reduction, as experimentally observed by cyclic voltammetry for a series of neutral and cationic functionalised bis(cyclopentadienyl) titanium(IV) derivatives, is metal based, involving the chemically and electrochemically reversible TiIV/TiIII… read more here.
Keywords: reduction; bis cyclopentadienyl; chemistry; neutral cationic ... See more keywords