Magnetic anisotropy and slow magnetic relaxation of seven-coordinate cobalt(II)–nitrate complexes
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.050
Abstract: Abstract Two seven-coordinate cobalt(II) complexes with the molecular formulae [Co(L)(NO3)2(CH3CN)] (L = 2,2′-bipyridine, 1; L = 1,10-phenanthroline, 2) were prepared and magnetically characterized. X-ray single crystal diffraction shows that 1 exhibit the distorted pentagonal bipyramidal geometry around the central… read more here.
Keywords: coordinate cobalt; seven coordinate; slow magnetic; magnetic relaxation ... See more keywords
(C5H6N)Pb2X5 (X = Cl, Br): Hybrid Lead Halides Based on Seven-Coordinate Pb(II).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00351
Abstract: Hybrid lead halides are a diverse family of compounds, of interest for their optoelectronic properties, that vary in the dimensionality and connectivity of their inorganic substructures. The great majority of these compounds are based on… read more here.
Keywords: hybrid lead; lead halides; geometry; seven coordinate ... See more keywords
A cyanide-bridged wheel featuring a seven-coordinate Mo(iii) center.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09373c
Abstract: A new cyclic molecule incorporating [MoIII(CN)7]4- has been characterized by single crystal X-ray methods, SQUID magnetometry and theoretical calculations. The wheel molecule [MoIII(CN)7]6[Ni(L)]12(H2O)6 exhibits ferromagnetic Mo-Ni coupling which did not exist for the previously reported… read more here.
Keywords: bridged wheel; wheel featuring; cyanide bridged; seven coordinate ... See more keywords
Tuning the ligand field in seven-coordinate Dy(iii) complexes to perturb single-ion magnet behavior
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DOI: 10.1039/d1nj00734c
Abstract: Two mononuclear seven-coordinate Dy(iii) complexes with different strengths of ligand fields exhibit different slow magnetic relaxations. read more here.
Keywords: iii complexes; coordinate iii; seven coordinate; tuning ligand ... See more keywords