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Seven copper (I) complexes of diphosphine ligands and N^N ligands: Syntheses, structural characterizations and spectroscopic properties

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Published in 2017 at "Polyhedron"

DOI: 10.1016/j.poly.2017.08.021

Abstract: Abstract The reactions of diphosphine ligands and nitrogen-containing ligands with Cu(I) salts in the mixed solvents of methanol (MeOH) and dichloromethane (CH2Cl2) generated the corresponding complexes, {[Cu(dppbe)(Bphen)](ClO4)·2CH3OH}n (1), {[Cu2(dppe)(dmp)2(CN)2]·2CH3OH}n (2), {[Cu2(dppb)(dmp)2I2]·2CH3OH}n (3), [Cu(POP)(C16H6N6)]I (4), {[Cu(POP)(C16H6N6)](SCN)}n… read more here.

Keywords: diphosphine ligands; seven copper; hydrogen bonds; bis ... See more keywords