Regioselective Gold-Catalyzed Hydration of CF3- and SF5-alkynes.
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DOI: 10.1021/acs.orglett.9b01379
Abstract: The regioselective gold-catalyzed hydration of CF3- and SF5-alkynes is described. The corresponding trifluoromethylated and pentasulfanylated ketones are obtained in up to 91% yield as single regioisomers showcasing the use of CF3 and SF5 as highly… read more here.
Keywords: cf3 sf5; cf3; sf5 alkynes; regioselective gold ... See more keywords