Reduction of SF5CF3via iridium catalysis: radical trifluoromethylation of aromatics.
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DOI: 10.1039/d3cc00495c
Abstract: The greenhouse gas SF5CF3 acts as CF3 source for the photocatalytic trifluoromethylation of arenes on using [Ir(dtbbpy)(ppy)2]PF6 (4,4'-di-tert-butyl-2,2'-dipyridyl, ppy = 2-phenylpyridine) as catalyst. The trifluoromethylation of C6D6 in the presence of 1-octanol results in the… read more here.
Keywords: catalysis radical; radical trifluoromethylation; sf5cf3via iridium; reduction sf5cf3via ... See more keywords