A Ferromagnetically Coupled, Bell-Shaped [Ni4Gd5] Cage.
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DOI: 10.1021/acs.inorgchem.9b00946
Abstract: Reaction between NiCl2·6H2O, 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), benzoic acid, and M(NO3)3·6H2O (M = Gd, Y) in MeCN under basic conditions yields the complexes [NiII4GdIII5(PhCOO)10(HL)4(HLzw)4(OH)2(NO3)2]Cl·13.6MeCN·H2O (1·13.6MeCN·H2O) and [NiII4YIII5(PhCOO)10(HL)4(HLzw)4(OH)2(NO3)1.5(H2O)0.5]0.5Cl(NO3)·3H2O (2·3H2O). Both clusters display similar structures, consisting of a bell-shaped… read more here.
Keywords: ni4gd5 cage; bell; shaped ni4gd5; ferromagnetically coupled ... See more keywords