Azo-oximate metal-carbonyl to metallocarboxylic acid via the intermediate Ir(III) radical congener: quest for co-ligand driven stability of open- and closed-shell complexes.
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DOI: 10.1039/d2dt00345g
Abstract: The redox non-innocent behavior of the diaryl-azo-oxime ligand LNOH1 has been accentuated via the synthesis of metastable anion radical complexes of type trans-[Ir(LNO˙-)Cl(CO)(PPh3)2] 2 (CO is trans to azo group of the ligand) by the… read more here.
Keywords: ligand; closed shell; trans lno; shell complexes ... See more keywords