Synthesis of Bicyclic P,S-Heterocycles via the Addition of Thioketones to a Phosphorus-Centered Open-Shell Singlet Biradical.
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DOI: 10.1021/acs.inorgchem.1c03207
Abstract: Formal addition reactions between the open-shell singlet biradical [P(μ-NTer)]2 (1Ter) and xanthione, thioxanthione, as well as ferrocenyl naphthyl thioketone were studied in detail. Reactions were performed at room temperature and led to the formation of… read more here.
Keywords: addition; shell singlet; thioketone; open shell ... See more keywords
Generation and Characterization of the Charge-Transferred Diradical Complex CaCO2 with an Open-Shell Singlet Ground State.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02768
Abstract: The CaCO2 complex is generated via the reaction of excited-state calcium atom with carbon dioxide in a solid neon matrix. Infrared absorption spectroscopy and quantum chemical calculations reveal that the complex has a planar four-membered… read more here.
Keywords: state; shell singlet; open shell; singlet ground ... See more keywords